Continuous Time Random Walks with Reactions Forcing and Trapping

School of Mathematics and Statistics, University of New South Wales, Sydney, Australia

^⋆ Corresponding author. E-mail: b.henry@unsw.edu.au

Abstract

One of the central results in Einstein’s theory of Brownian motion is that the mean square displacement of a randomly moving Brownian particle scales linearly with time. Over the past few decades sophisticated experiments and data collection in numerous biological, physical and financial systems have revealed anomalous sub-diffusion in which the mean square displacement grows slower than linearly with time. A major theoretical challenge has been to derive the appropriate evolution equation for the probability density function of sub-diffusion taking into account further complications from force fields and reactions. Here we present a derivation of the generalised master equation for an ensemble of particles undergoing reactions whilst being subject to an external force field. From this general equation we show reductions to a range of well known special cases, including the fractional reaction diffusion equation and the fractional Fokker-Planck equation.